I was under the impression that hot water freezes first
If you have equal volumes of boiling and room temperature water in a container the hot water can actually freeze faster.
I reckon that there are some good reasons for it aswell:
Convection is one, when some of the water cools at it will mix with the hotter water bringing down the temperature.
Evapourtion is another one to be taken in to account the boiling water will loose some of its volume
It can depend on the container and its insulating values aswell.
That would be my impression but im not entirely sure