Jump to content

ppdj

New Members
  • Posts

    1
  • Joined

  • Last visited

Everything posted by ppdj

  1. Hi all, I need help in determining the mechanism for the thionation of lactones by P4S10 + hexamethyldisiloxane. The specific paper I am referring to is Curphey, T. J. J. Org. Chem. 2002, 67, 6461-6473. The author there mentions about oxygenating the P4S10 initially, followed by the cleavage of P-O-P units by hexamethyldisiloxane. What I don't understand is how to show this transformation by arrows for something like 7-membered lactone. Any help on this would be greatly appreciated.
×
×
  • Create New...

Important Information

We have placed cookies on your device to help make this website better. You can adjust your cookie settings, otherwise we'll assume you're okay to continue.