I think its more of biochemical issue. I don't think post-mortem analysis will result in any unique findings. Fair disclaimer here, I have no in-depth knowledge on dissection, but it is my understanding that the tissues will not be changed drastically as a result of biochemical malfunction. However, there was a case in early 2000s where a man had acquired an egg-sized brain tumor in the right orbitofrontal region and suddenly began exhibiting characteristics of pedophillia. Once the tumor was removed, his urges went away and later on returned when the tumor grew back. I haven't found any articles discussing the hormonal changes that his tumor may have caused. But then again, ANY kind of sexual deviance and sociopathic behaviors have been linked to issues in the frontal lobe. I guess it's all dependent on the individual.
Biological disorders shouldn't affect one's morality. They can make morals harder to attain, but at the end of the day, people are going to do what they want. The man with the tumor was also experiencing difficulties with other tasks, he lost a substantial amount of brain matter. He was essentially becoming mentally incapacitated, therefore he was truly incapable of understanding his own actions.