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Everything posted by DQW
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In diatomic (and linear triatomic) molecules, the moment of inertia about the internuclear axis is negligible.
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The high specific heat capacity of Li is due to Dulong and Petit (in a crystalline solid the number of available modes is constant). The high specific heat of water is essentially due to the fact that it is one of the lightest non-linear molecules. As far as I know, only ammonia (NH3), has a higher specific heat at RT - as is expected.
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First approach : Use the condition for equal slopes. This gives 2ax = 1 or x = 1/2a. From this, you have the point of intersection in terms of 'a', which you can plug into the equation for the parabola and solve for 'a'.
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Alternative approach : For a line to be tangent to a curve, the line and curve must have exactly one point of intersection. The points of intersection between the two is clearly given by the quadratic equation got from eliminating y between the two equations. What is the condition for a quadratic equation to have exactly one real solution ? PS : 'a' is not 1/2
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The absorption and re-radiation from solid and liquid objects
DQW replied to JoeMK's topic in Homework Help
What ideas do you have? Tell us what you think, and we'll suggest improvements or corrections, if required. -
A necessary condition for a line to be a tangent at some point of a curve is that the line have the same slope as the curve does at that point.
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Centrifugal force created by the Earth's rotation
DQW replied to Kyrisch's topic in Classical Physics
At the equator, [imath]v^2/Rg \approx 0.3 [/imath]%. -
Pinning Force & Electromagnetic Drag Force
DQW replied to labview1958's topic in Modern and Theoretical Physics
Flux pinning in a Type II SC happens when the SC is in the Abrikosov phase. This is a phase that is intermediate to the Meissner phase and the normal phase. When you increase the temperature or field from the Meissner phase in certain types of SCs, the SC finds that it is energetically less expensive to partially allow some of the field through it (than to exclude the entire field or allow the entire field). So, rather than remain in the perfect Meissner phase or turn completely into a normal material, the SC nucleates tiny lines of normal material that carry flux through them. In a perfectly defect-free SC crystal, these lines, known as flux vortices, arrange themselves along a triangular lattice. However, in a real material (with impurities and defects), these vortices get pinned at the locations of these defects. This is what is known as flux pinning in Type II SCs, and is what helps stabilize a levitation demo. -
http://www.chemistrycoach.com/quantum.htm http://hyperphysics.phy-astr.gsu.edu/hbase/qunoh.html http://chemed.chem.purdue.edu/genchem/topicreview/bp/ch6/quantum.html http://scienceworld.wolfram.com/physics/QuantumNumbers.html
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Yes there is a big difference. For hydrogenlike atoms/ions, the energy depends only on the principal quantum number 'n'. This relationship is what Tom wrote out (following the Bohr picture). For any value 'n' of the principal quantum number, there are n allowed values of the angular momentum quantum number 'l' (from 0 to n-1). It is these numbers that are designated s (l=0), p (l=1), d (l=2), f (l=4), ... by spectroscopists. The principal quantum number does not determine angular momentum. And in multielectron atoms (in the absense of applied fields), the energy depends both on 'n' and 'l'.
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One thing that comes close to an answer, in the spirit that I imagine this question was intended is the speculation that you can have communication between a pair of nanodevices on a chip, by placing them at the foci of a quantum corral. http://www.scienceforums.net/forums/showthread.php?t=5230 Another answer that comes to mind is the possible use of photon polarizations to designate binary bits to achieve encrypted communication that overcomes the key distribution problem. http://www.scienceforums.net/forums/showthread.php?t=13255
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The safest place would be at the ends. The "unsafest" would be in the middle. This can be intuited from a symmetry argument, but can also be reasoned out pretty unmessily (just cumbersome to LaTeX it all out). Particularly, notice that contributions from separations greater than L/2 are smaller than those from separations smaller than L/2. This will demonstrate that x=L/2 provides the maximum probability of getting hit. A similar argument tells you that the ends are the safest. The trick is in adding amplitudes - that's all.
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It's about this :
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Okay, I get what you're saying now. But the transmission of radiation by a transparent medium is not given by the Stefan-Boltzmann Law. That only talks about radiation from a heated surface. The energy transmitted through a transparent medium is a function of the transmission coefficient, not the emissivity. Oh, wait, you're treating the inside surface of the glass window as the radiator ? I'm not sure I see how exactly that works, but I haven't really given it much thought.
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I can't say I agree with this - it is completely unphysical. If the outside of the wall is assumed to be at T(out) - this is the assumption you make in justifying the conduction equation as written by Sarah - there will be NO radiation. And if the outside wall is assumed to be at T(in) - this is the assumption made in writing the radiation equation in that form - there will be no conduction. As, I said before, conduction and radiation are not processes that happen in parallel here. "Adding them up" makes no sense to me (and this answer will be an overestimate; albeit by a fraction comparable to P(rad)/P(cond) as calculated by Sarah).
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Theoretical question about electromagnetic radiation...
DQW replied to Jonsy123's topic in Quantum Theory
I'm not sure what mezarashi means by this interaction "from a distance". I am talking about specular reflection - which, if I'm not mistaken (and I could be), is not empirically different from diffuse reflection at the microscopic scale. Diffuse reflection, in my opinion, is merely a macroscopic effect arising from surface topographical features. For a metal, the Fresnel reflectance is essentially a constant (angle independent), and reduces to Snell's Law. Also, for a metal, one can easily derive Snell's Law from a simple calculation based on the Maxwell Equations (and angle conservation comes directly from requiring that the tangential component of the E-field be continuous at an interface). However, this classical explanation provides little intuition for the mechanism at a microscopic level. As you refine your models and go from a classical model to QM to QED..., you have different explanations that approximate the real phenomenon to different extents. For a simple semiclassical treatment, see Feynman's Lectures Vol 2 Ch. 32. Also see http://en.wikipedia.org/wiki/Plasmon -
Theoretical question about electromagnetic radiation...
DQW replied to Jonsy123's topic in Quantum Theory
The photon is actually absorbed and re-emitted. It is absorbed by one of the conduction electrons. This transfer of energy and momentum to the conduction electron creates a longitudinal compression wave within the conduction ("free") electrons. So, the impinging photon causes the plasma of free electrons to compress and the flex back (at the natural frequency of the free electron gas) spitting out a photon identical to the incident one. -
No, sarah, that's not correct. The correct answer will be what you get from following some nerd's suggestion (post #5). Unforunately, this does give you a 4th order polynomial. If you're clever, you can use a Taylor expansion and throw away high order terms and make life easier for yourself. Conduction through the pane and radiation off its surface are processes in series not in parallel. You can not add them up.
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Theoretical question about electromagnetic radiation...
DQW replied to Jonsy123's topic in Quantum Theory
That's essentially correct, but not entirely. The most important effect of increasing temperature is that you now populate states that were unoccupied at lower temperatures - specifically some of the states above E(F) in the picture below. In any case, this is more or less irrelevant to reflection off a metallic surface. -
Theoretical question about electromagnetic radiation...
DQW replied to Jonsy123's topic in Quantum Theory
Yes, I did - in the context of reflection at least. There are processes like x-ray photoemission (of core electrons) that deal with individual atoms, but that's not what we're talking about here. -
Theoretical question about electromagnetic radiation...
DQW replied to Jonsy123's topic in Quantum Theory
Absolutely. And at frequencies below the plasma frequency, you will have every one of your incident frequencies be reflected, not just certain special frequencies. And this is not realy because you have a band of energies but because you are exciting collective oscillatory modes known as plasmons - kind of like bouncing a steel ball off a rubber floor. -
The nexusmagazine article is pretty funny. One person who I suspect mightn't have appreciated the humor would be Pauli. He would have been furious that some bloke was giving Einstein the credit for predicting the neutrino. Grrr...
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Bush wants Intelligent Design as Alternative to Evolution
DQW replied to Tetrahedrite's topic in Politics
Rick Santorum is a #$&^%$, IMO, but that's besides the point. Just a few days ago, when I was talking about this wth friends, they were speculating that Bush will perhaps throw the left some scraps (as a trade) in the form of loosening up little on stem cell research. I was highly sceptical. And I was right. http://news.bbc.co.uk/2/hi/americas/4567253.stm The more I read stuff like this and the fact that the Republican political machine is pushing Lynn Swann (yikes!!) to run for Goernor in PA, makes me believe more strongly in the Puppet Theory of Right Wing politics. -
YT : As I explained in my previous pair of posts. You alter the photon polarization only if you do not know what the polarization is (and hence use an arbitrary filter). And with any given filter, the best you can do is eliminate one polarization - namely the one normal to the filter orientation. But if you are told that the polarization is along one of two normal directions, then you can eliminate one direction and hence determine the polarization direction. This is essentially what JohnWB's evesdropper "Eve" has achieved. So, it is possible for Eve to intercept the message and prepare an identical message. The only difficulty I can see, will be in making up for the time lag. In theory, this difficulty could be overcome by transmitting over air (conventionally) for some distance.