You could, one way or the other, remove electrons from metals. But soon you'd see the metal fall apart, since the binding electrons are those you'd be shooting away. This would also be an inefficient way of 'extracting' energy, since the kinetic energy imposed on the electrons would originate in the field you used to extract them. It would get progressively harder to get the negatively charged electrons to leave the increasingly positively charged metal. Also, I can't see how a magnetic field would be useful, since it, to my knowledge, only propels already moving charges in circles. The field of an incredibly large positive charge might be suited for the purpose.
All of this is not at all practical, and not even close to useful, unfortunately.