but ones said that
electrochemical series of the discharge of OH- or Ag is not the only factor. The concentration of the solvent, nature of electrode are also important. So to speak, very high [Ag+] & [NO3-] means relatively low concentration of [OH-] & [H+]. So comparatvely, the conc. of Ag(s) here is far higher than that of OH-, so it discharge perferentially. Second, metal electrode, such copper, silver, may enhance the release of ions especially ions like Cu, Ag, Ni, etc.
but is the effect of concentration apply to the "solid" silver anode too? not only apply to ions in the solution!?