NaNO3 is a good idea although I haven't tried it.
I had KNO3 which has a slightly higher mp (350 C I think)
Electrolysis is very slow. I had the idea to add another salt to it.
KCl was not available to me so I had to use KI.
Damn iodine vapors! Although they condensed and I had some nice crystals on the glass walls.
Electrolysis was quite fast and I was able to produce K.
I used a iron rod as cathode and a glass envelope to seal the K. I dropped a water droplet and sparks flew. I dropped some more, more sparks.
I poured water and the stuff warmed up and that's all.
Oh yes, anode was graphite rod. That stuff desintegrates.
Any damn material you might use as anode will desintegrate I guess.
Perhaps a few mg of K produced. It is very tough to produce this elements.
Have plenty of propane or whatever you use ready.
And be smart when you do this. Protect your eyes.