At Warwick we have a mentoring scheme for A-level students who study maths, and it basically involves a student asking a question about some sort of topic (by e-mail), and then an undergraduate - their mentor - would respond with either a hint to help them, or a fully fledged answer. This is a bit different from the normal forums, as mentoring only involves the two people involved - when a person posts a question on the forums, anyone can answer.
I daresay we could use private messages instead of e-mail (and take advantage of the latex system that will hopefully be put in place either today or tomorrow, whenever blike's free ).