well, I'm not trying to make a crank violation of the second law, but this is a kind of thought experiment, I am assuming we created a gas that ionizes at room temperature due to the thermal energy of the atmosphere alone, although far from existence, there is no connection between the validity of the second law and the ability to create such a kind of gas, Or there is?
well, my assumption is: we have some type of gas which becomes a plasma at -say- 0 degrees, you need no energy input to make plasma in the first place because the thermal energy in the atmosphere is enough to ionize our gas and turn it into plasma, so, whatever energy you get it won't be useless, if you could harness only 1% of the radiated power you have absorbed some energy from the atmosphere, thus deviated from thermal equilibrium without exerting external work, which necessarily violates the second law of thermodynamics.