I got to this site looking for confirmation of a description in Jared Diamond's book Why is Sex Fun? (pg 43) that describes the mechanics of how one type of "pseudohermaphrodite looks like a normal woman. Indeed 'she' conforms to the male ideal of female pulchritude even more closely than does the average woman." (in particular long legs and large breasts) and cites "repeated" cases of beautiful woman fashion models turning out to be men.
There don't seem to be many references for a science site....
Looks like we are talking about complete androgen insensitivity syndrome:
http://en.wikipedia.org/wiki/Androgen_insensitivity_syndrome
Sorry, no links to TV shows