It is true that compounds such as wollastonite, CaSiO3, are common in the Earth's crust, but do you have any idea how much energy it would require not just to mine it, as bob000555 pointed out, but process it. The covalent and ionic bonds in Ca-bearing silicates is exceedingly strong, and I would suggest that you would probably produce around 5x as much CO2 in the energy required than you would extract.
It is possible you could use gypsum, CaSO4, but once again mining it would probably get you back where you started (not to mention the world's gypsum supplies would probably be exhausted, a you also have a problem with disposing of the sulfuric acid you would produce.
The world's scientists have considered this type of thing before, but have concluded it is unviable. The problem won't be solved by a high school science student with a poor grasp of chemistry.