Missvici101 Posted November 10, 2017 Posted November 10, 2017 Hello, I need to calculate the yield % of [(Ph)3PH]2[CoCl4] The actual yield is 2.715g My issue is with the theoretical yield, here is how I did it: I'm following this reaction that was given in the explanations of my homework; (C6H5)3P + HCl => (C6H5)3PH+ + Cl- Molar mass of (C6H5)3P: 262.29 g/mol Molar mass of (C6H5)3PH+: 263.30 g/mol Mass of Triphenylphosphine measured: 1.062 g n(triphenylphosphine)=m(triphenylphosphine)/M(triphenylphosphine) =1.062g/(262.29 g/mol)=4.049×10-3 mol Molar mass of [(Ph)3PH]2[CoCl4] : 727.33 g/mol Since there are 2 molecules of (Ph)3PH in the [(Ph)3PH]2[CoCl4], the n(triphenylphosphine) needs to be divided by 2. n([(Ph)3PH]2[CoCl4])=n(triphenylphosphine)/2=2.025×10-3 mol m[(Ph)3PH]2[CoCl4] =n[(Ph)3PH]2[CoCl4] ×M[(Ph)3PH]2[CoCl4] m[(Ph)3PH]2[CoCl4] =(2.025x10-3 mol)×(727.33 g⁄mol) m[(Ph)3PH]2[CoCl4] =1.479 g = Theoretical yield You see, my theoretical yield is smaller than my actual yield. If someone sees my mistake, please let me know. Thank you, MV101
BabcockHall Posted November 11, 2017 Posted November 11, 2017 It would help the clarity of your question if you defined n, m, and M clearly and unambiguously.
Missvici101 Posted November 11, 2017 Author Posted November 11, 2017 n is the # of moles. m is the mass of the measured samples M is the Molar mass of the comound.
BabcockHall Posted November 11, 2017 Posted November 11, 2017 So far, I have not found an error. I did see one thing that bothered me a bit, and it could be a clue. It is difficult to see how the protonated form of a phosphine could be a ligand to the metal ion. The unprotonated form would be fine.
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