beecee Posted February 26, 2019 Posted February 26, 2019 https://phys.org/news/2019-02-nasa-life-ocean-floor.html NASA study reproduces origins of life on ocean floor February 26, 2019, NASA: Scientists have reproduced in the lab how the ingredients for life could have formed deep in the ocean 4 billion years ago. The results of the new study offer clues to how life started on Earth and where else in the cosmos we might find it. Astrobiologist Laurie Barge and her team at NASA's Jet Propulsion Laboratory in Pasadena, California, are working to recognize life on other planets by studying the origins of life here on Earth. Their research focuses on how the building blocks of life form in hydrothermal vents on the ocean floor. To re-create hydrothermal vents in the lab, the team made their own miniature seafloors by filling beakers with mixtures that mimic Earth's primordial ocean. These lab-based oceans act as nurseries for amino acids, organic compounds that are essential for life as we know it. Like Lego blocks, amino acids build on one another to form proteins, which make up all living things. Read more at: https://phys.org/news/2019-02-nasa-life-ocean-floor.html#jCp the paper: https://www.pnas.org/content/early/2019/02/19/1812098116 Redox and pH gradients drive amino acid synthesis in iron oxyhydroxide mineral systems: Significance: Amino acids are formed from simple organic precursors in iron oxyhydroxide mineral systems that contain geochemical gradients. Redox and pH gradients significantly impact reaction pathways: Amino acids only form when the mineral contains both oxidized and reduced iron, and when the surrounding solution is alkaline. This shows that aqueous, partially reducing iron mineral systems (which would have been common in early-Earth seafloor/vent environments) could have facilitated synthesis and concentration of prebiotic organic molecules relevant for the emergence of life. It also suggests that geochemical gradients in vent environments can drive product selectivity for prebiotic chemistry, perhaps leading to more complex organic reaction systems as these molecules continue to diffuse and react under different conditions within the gradients. Abstract: Iron oxyhydroxide minerals, known to be chemically reactive and significant for elemental cycling, are thought to have been abundant in early-Earth seawater, sediments, and hydrothermal systems. In the anoxic Fe2+-rich early oceans, these minerals would have been only partially oxidized and thus redox-active, perhaps able to promote prebiotic chemical reactions. We show that pyruvate, a simple organic molecule that can form in hydrothermal systems, can undergo reductive amination in the presence of mixed-valence iron oxyhydroxides to form the amino acid alanine, as well as the reduced product lactate. Furthermore, geochemical gradients of pH, redox, and temperature in iron oxyhydroxide systems affect product selectivity. The maximum yield of alanine was observed when the iron oxyhydroxide mineral contained 1:1 Fe(II):Fe(III), under alkaline conditions, and at moderately warm temperatures. These represent conditions that may be found, for example, in iron-containing sediments near an alkaline hydrothermal vent system. The partially oxidized state of the precipitate was significant in promoting amino acid formation: Purely ferrous hydroxides did not drive reductive amination but instead promoted pyruvate reduction to lactate, and ferric hydroxides did not result in any reaction. Prebiotic chemistry driven by redox-active iron hydroxide minerals on the early Earth would therefore be strongly affected by geochemical gradients of Eh, pH, and temperature, and liquid-phase products would be able to diffuse to other conditions within the sediment column to participate in further reactions.
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