Jump to content

Recommended Posts

Posted

the chemical name of 2,3-dimethyl butane has structure with a ch3 up and down. is it possible for both to be up? what is the name given to that? do the have same/similar properites or different?

new.png

original.png

Posted (edited)
1 hour ago, observer1 said:

the chemical name of 2,3-dimethyl butane has structure with a ch3 up and down. is it possible for both to be up? what is the name given to that? do the have same/similar properites or different?

new.png

original.png

They are the same, because rotation around a single bond is possible -  unless there are specific steric hindrances from very large substituents, which a methyl group is not.

Don't forget that the bonds in an sp3 hybridised C atom project in 3D, towards the corners of a tetrahedron. They don't stick out at 90 degrees in a plane, as shown in typical 2D representations like those in your example.

If there were a double bond between C2 and C3 then rotation would not be possible and you could then speak of cis and trans isomers, depending on whether the substituents were on the same side or on opposite sides.

In an sp2 hybridised C. atom, there are 3 bonds at 120degrees to each other in a plane, one or more of the bonds having some double bond character. 

 

Edited by exchemist
Posted
2 hours ago, exchemist said:

They are the same, because rotation around a single bond is possible -  unless there are specific steric hindrances from very large substituents, which a methyl group is not.

Don't forget that the bonds in an sp3 hybridised C atom project in 3D, towards the corners of a tetrahedron. They don't stick out at 90 degrees in a plane, as shown in typical 2D representations like those in your example.

If there were a double bond between C2 and C3 then rotation would not be possible and you could then speak of cis and trans isomers, depending on whether the substituents were on the same side or on opposite sides.

In an sp2 hybridised C. atom, there are 3 bonds at 120degrees to each other in a plane, one or more of the bonds having some double bond character. 

 

+1

Create an account or sign in to comment

You need to be a member in order to leave a comment

Create an account

Sign up for a new account in our community. It's easy!

Register a new account

Sign in

Already have an account? Sign in here.

Sign In Now
×
×
  • Create New...

Important Information

We have placed cookies on your device to help make this website better. You can adjust your cookie settings, otherwise we'll assume you're okay to continue.