granpa Posted March 13, 2009 Posted March 13, 2009 spin of electron=s=1/2 S=(h/2π)*√s(s+1) μs=S*gs*q/2m gs=2 l=0 or 1 or 2 ... up to n-1 L=(h/2π)*√l(l+1) μL=L*gL*q/2m gL=1 net magnetic moment of electron in subshell l = μs + μL is this correct? Merged post follows: Consecutive posts mergedalso do the 2 components have the same sign? is the sum greater than or less than the magnetic moment due to spin alone?
swansont Posted March 13, 2009 Posted March 13, 2009 Looks right. You can double-check http://en.wikipedia.org/wiki/Electron_magnetic_dipole_moment The sum depends on the spin orientation and projection of the orbital term— there are rules for adding angular momentum vectors, but this is simplified by having only a spin-1/2 particle involved http://en.wikipedia.org/wiki/Angular_momentum#Addition_of_quantized_angular_momenta So you'll have L +/- 1/2 states, e.g. an electron in an L=1 state is going to have either J=1/2 or 3/2
granpa Posted March 13, 2009 Author Posted March 13, 2009 that website has changed since I took my notes. it hasnt become any clearer. so if we restrict ourselves to talking about the component of magnetic moment in any one direction (the z direction) then the math becomes very much simpler. μB=the bohr magneton (a unit magnetic moment) for spin: μz=-gsμBms gs≅2 ms=1/2 for orbital magnetic moment: μz=-gLμBmL gL=1 mL=l,l-1,...,-l Merged post follows: Consecutive posts mergedhere is an excellent article on the magnetic moment of electrons: http://www.shef.ac.uk/physics/teaching/phy332/atomic_physics6.pdf
Severian Posted March 13, 2009 Posted March 13, 2009 It is only approximately right. gs isn't exactly 2.
granpa Posted March 16, 2009 Author Posted March 16, 2009 that website has changed since I took my notes. it hasnt become any clearer. so if we restrict ourselves to talking about the component of magnetic moment in any one direction (the z direction) then the math becomes very much simpler. μB=the bohr magneton (a unit magnetic moment) for spin: μz=-gsμBms gs≅2 ms=1/2 for orbital magnetic moment: μz=-gLμBmL gL=1 mL=l,l-1,...,-l Merged post follows: Consecutive posts mergedhere is an excellent article on the magnetic moment of electrons: http://www.shef.ac.uk/physics/teaching/phy332/atomic_physics6.pdf yet mj=ml+ms not mj=ml+2*ms even though gs≅2
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