budullewraagh Posted November 30, 2004 Posted November 30, 2004 anybody here familiar with ferrates? supposedly barium superoxide and Fe2O3 yield BaFeO4... as well, molten KNO3 and Fe2O3 should yield K2FeO4 but hey, since when could iron chemically oxidize to +6??
chadn Posted November 30, 2004 Posted November 30, 2004 but hey, since when could iron chemically oxidize to +6?? Apparrently forever.
budullewraagh Posted November 30, 2004 Author Posted November 30, 2004 well, had you heard previously of this? supposedly it works...the thought of it is astounding, as such would be an amazing oxidizing agent.
Tetrahedrite Posted December 1, 2004 Posted December 1, 2004 Iron can have oxidation states 0, 2+, 3+, 4+, 5+, and 6+.
budullewraagh Posted December 1, 2004 Author Posted December 1, 2004 right, but you almost never see them. according to one of my books, iron can be found as Fe-2 in Fe(CO)4-2, as Fe-1 in Fe2(CO)8 -2 as Fe+ in [Fe(NO)(H2O)5]+2, as Fe+2 in FeO, FeS2, FeF2, etc, as Fe+3 in Fe2O3, Fe3O4, FeF3, FeO(OH), as Fe+4 in some rare complexes and FeO4-2 and as +5 in FeO4-3...doesn't mention +6 must be really rare i guess i have a project for when my KOH(s) comes
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