nemzy Posted January 20, 2005 Share Posted January 20, 2005 Why is it necessary to use a large excess of acetic adic in the prepartion of isopentyl acetate? Link to comment Share on other sites More sharing options...
budullewraagh Posted January 20, 2005 Share Posted January 20, 2005 mmm, banana oil...enrages bees... it isnt necessary actually. i take it you are doing the esterfication of isopentanol and acetic acid? they say they want an excess of acetic acid i believe because you want the hydronium cations as a catalyst. do it in the presence of another (prefferably mineral) acid and you'll be set Link to comment Share on other sites More sharing options...
shryocdj Posted April 21, 2006 Share Posted April 21, 2006 why is it necessary to have an acid catalyst in the presence of acetic acid? and I thought that the reason you overload on the acetic acid is to shift the easily reversible equilibrium. my second question is why NaHCO3 is used? does it also shift the equilibrium or remove one of the biproducts? Link to comment Share on other sites More sharing options...
Darkblade48 Posted April 22, 2006 Share Posted April 22, 2006 The mineral acid is merely a source of readily available protons that are needed to catalyze the Fischer esterification. Sodium bicarbonate is used to remove the remaining acid that has not reacted. Link to comment Share on other sites More sharing options...
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