Elite Engineer Posted November 27, 2013 Posted November 27, 2013 I'm considering psaaing sulfur dioxide through pvc piping under pressure in order to make sulfuric acid. Does sulfur dioxide react with the make-up of pvc piping?
Enthalpy Posted November 27, 2013 Posted November 27, 2013 At room temperature but not +60°C, PVC is given as resistent to sulphur dioxide by the manufacturers: https://www.spilltech.com/wcsstore/SpillTechUSCatalogAssetStore/Attachment/documents/ccg/CBOOM.pdf plus ipexinc and more, google: PVC "sulfur dioxide" compatibility Though, I would NOT use a Pvc pipe for pressure, with any fluid. I trust only metals for pressure, or fibers. Worse, Pvc is brittle, as opposed ot polypropylene. You don't want a deadly leak when a rock or a tree falls on your pipe, do you? Regulations forbid it probably. In case you want to stress a plastic, please remember that its long-term resistance is very different from its short-term proof stress: easily 5 or 10 times less.
Elite Engineer Posted November 28, 2013 Author Posted November 28, 2013 Though, I would NOT use a Pvc pipe for pressure, with any fluid. I trust only metals for pressure, or fibers. Worse, Pvc is brittle, as opposed ot polypropylene. You don't want a deadly leak when a rock or a tree falls on your pipe, do you? Regulations forbid it probably. In case you want to stress a plastic, please remember that its long-term resistance is very different from its short-term proof stress: easily 5 or 10 times less. I did some more research, I'm going to use copper tubing..I don't know why I thought of pvc piping, as the tubing will actually go through sulfric acid
AbeMichelson Posted December 25, 2013 Posted December 25, 2013 Sulfuric Acid + Copper -> Copper Sulfate! If Sulfur Dioxide is around any water it will form sulfuric acid. I would go with stainless steel. It is your safest bet.
Sensei Posted December 25, 2013 Posted December 25, 2013 If Sulfur Dioxide is around any water it will form sulfuric acid. Sulfurous acid, H2SO3 (H2O + SO2 -> H2SO3) Sulfuric acid is H2SO4 You can use Hydrogen peroxide H2O2 to create H2SO4
Moontanman Posted December 25, 2013 Posted December 25, 2013 I'd go with CPVC at least, it's high temperature resistant and corrosion resistant... http://en.wikipedia.org/wiki/Chlorinated_polyvinyl_chloride
Enthalpy Posted December 25, 2013 Posted December 25, 2013 Plastic pipes and pressure? Beware! Here a corrosion table for sulfur dioxide and metals: http://www.google.de/search?q=%22Sulfur+dioxide%22+Copper+compatibility&ie=utf-8&oe=utf-8&rls=org.mozilla:fr:official&client=firefox-a&gws_rd=cr&ei=NRO7UpzZOMebtAbd9IH4AQ "stainless steel" isn't precise enough.
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