The_goosse Posted April 6, 2015 Posted April 6, 2015 Please refer to the attached file. Can any one please explain to me where the (x-0.01) for O2 comes from? I have been stuck here for a long time. Thanks.
pavelcherepan Posted April 6, 2015 Posted April 6, 2015 Can you see that first term on the left is CO and on the right - CO2? And all other reagents are the same.
pavelcherepan Posted April 6, 2015 Posted April 6, 2015 (edited) Now try and count oxygens on both sides of the equation. Are they the same? Another question - how do you reckon CO became CO2? Edited April 6, 2015 by pavelcherepan 1
The_goosse Posted April 6, 2015 Author Posted April 6, 2015 On the left O2 it is; 2(x) + 0.02 and on the right O2 is; 0.04 + 2(x-0.01) which is 2(x) + 0.04 - 0.02 so the answer is yes. Not sure about the other question? Because of the combustion process? 1
pavelcherepan Posted April 6, 2015 Posted April 6, 2015 Well done. So CO here is not very stable in normal conditions so as soon as there was a chance it grabbed an oxygen atom from the air and got reduced to stable CO2.
studiot Posted April 6, 2015 Posted April 6, 2015 +1 each for good communications. I strongly suggest you don't use fractions or decimals in chemical equations (for balancing). Multiply through by 100 first. Each coefficient ie supposed to stand for one molecule (or 1 gram mole or 1 kgmole). As to pavel's second helpful question. You have (correctly) called this a combustion process. Combustion is combining with oxygen (oxidation). So what burns?
The_goosse Posted April 6, 2015 Author Posted April 6, 2015 I'm struggling with understanding how to get (x-0.01) for the products of oxygen. If I were given; 0.02 CO + (x) o2 + 3.76 (x) N2 > 0.02 CO2 + (??) O2 + (??) N2 I have no issue balancing the carbon I just struggle with the oxygen I have complete brain freeze!! Apologies if I have already answered this I just don't see it. Thanks again.
pavelcherepan Posted April 6, 2015 Posted April 6, 2015 (edited) On the left O2 it is; 2(x) + 0.02 and on the right O2 is; 0.04 + 2(x-0.01) which is 2(x) + 0.04 - 0.02 so the answer is yes. Not sure about the other question? Because of the combustion process? Look at this. You've already solved everything. The last step left is to put = sign between left and right sides and find x. To make it easier use studiot's advice and multiply both sides by a 100. Nitrogen doesn't participate in the reaction so you can forget about it for now. Edited April 6, 2015 by pavelcherepan
The_goosse Posted April 6, 2015 Author Posted April 6, 2015 ... thanks guys. I just can't see where the (x-0.01) comes from, for the example I have shown the (x-0.01) is given so where did it come from? I will figure it out eventually. Hi studiot, are there any occasions when it would be unacceptable to use the x100 rule to get rid of the fractions? Cheers. ... when I set each side = to each other I get the following for L and R hand side (Ignoring N as stated) 0.02 + 2(x) = 0.04 + 2(x) So where does this (x-0.01) come form? should it be; 0.02+2(x) = 0.04, therefor x=0.01 I dont know why I am so stuck on such a simple example relative to the rest of the material it doesn't get any simpler than this lol. I cant see the wood for looking at the trees. (as they say)
studiot Posted April 6, 2015 Posted April 6, 2015 (edited) So what happened to my post#7? Did I waste my time? Edited April 6, 2015 by studiot
The_goosse Posted April 6, 2015 Author Posted April 6, 2015 I don't know what burns right now studiot. This question burns actually. Unless you are referring to the fractions? I fully intend to use the x100 rule as soon as I have figured this one out. I will start again using the x100 rule and compare answers giving myself confidence that it works out the same either way. Not that I doubt you of course I just like to make sure I can do it another way before I change the way I already know. PS did you see my question in post #10?
studiot Posted April 6, 2015 Posted April 6, 2015 The answers to all your questions were in my post #7. Multiplying through by 100 was just meant to make life easy for you. So after a good laugh at your joke, what burns?
studiot Posted April 6, 2015 Posted April 6, 2015 (edited) Studiot Combustion is combining with oxygen (oxidation). So what burns? Remember this is your title to the thread, not mine. the_goosse the carbon? The carbon is oxidized. also I don't see any carbon in this. So what burns? Hint I could set light to it with a match and it used to be a component of town or producer gas, before the days of natural gas. http://en.wikipedia.org/wiki/Producer_gas Edited April 6, 2015 by studiot
The_goosse Posted April 6, 2015 Author Posted April 6, 2015 ... O2 I hope this is leading somewhere... lol
studiot Posted April 6, 2015 Posted April 6, 2015 I hope this is leading somewhere... lol Down the pub? Did you look at my link first?
The_goosse Posted April 6, 2015 Author Posted April 6, 2015 ... yes read it now. Carbon monoxide is the fuel is this what you mean? I am confused now its been a long day. I will pick this up in the morning. I have two weeks off work to study. Looks like I am going to need it. Cheers.
studiot Posted April 6, 2015 Posted April 6, 2015 (edited) REad through your equation and ask yourself What does it say in words? Never mind the numbers (stochiometry) for the moment. Just what is happening. Something along the lines of ___?___combines with _____?____ in the presence of _____?_____ And I hope we are now agreed that combines with oxygen = burns. Edited April 6, 2015 by studiot
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